The crystal problem for polytypes

Dowman P. Varn
Department of Physics and Astronomy, University of Tennessee, Knoxville

Geoffrey S. Canright
Department of Physics and Astronomy, University of Tennessee, Knoxville
Department of Physics and Astronomy, Indiana University



Abstract:

Recent work on discrete classical problems in one-dimensional statistical mechanics has shown that, given certain elementary symmetries, such problems may not have a periodic (crystalline) ground state, even in the absence of fine tuning of the couplings. Here these results are applied to several families of well known polytypic materials. The families studied are those represented by the compounds silicon carbide, cadmium iodide, gallium selenide, and also the micas and kaolins. For all families but silicon carbide it is found that there is a finite probability for the ground state to be degenerate and disordered.

A copy of this paper in pdf format: The crystal problem for polytypes

Publisher's web site: Acta Crystallographica Section A: Foundations of Crystallography

Citation: D.P. Varn and G.S. Canright, Acta Crystallogr., Sec A 57 (2001) 4 - 19.

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Last updated: 26 April 2009. Copyright © 2008-2010 by Dowman P. Varn. Contact: dpv@ComplexMatter.org

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